Acid Base Indicators

Indicator

pH Range

Colour Change

Preparation

Methyl violet

0.0

1.0

yellow

blue

0.01-0.05% in water

Crystal violet

0.0

1.8

yellow

blue

0.02% in water

Ethyl violet

0.0

2.4

yellow

blue

0.1% in 50% methanol/water

Malachite green
0.2
1.8
yellow
blue-green
water
Methyl green

0.2

1.8

yellow

blue

0.1% in water

2-(p-dimethylaminophenylazo)pyridine

0.2

1.8

yellow

blue
0.1% in ethanol
2-(p-dimethylaminophenylazo)pyridine

4.4

5.6

red

yellow
0.1% in ethanol
Cresol Red (o-cresolsulfonephthalein)

0.4

1.8

yellow

red

0.1% in 0.001048 M NaOH(aq)

Cresol Red (o-cresolsulfonephthalein)

7.0

8.8

yellow

red

0.1% in 0.001048 M NaOH(aq)

Quinaldine Red

1.0

2.2

colourless

red

1% in ethanol

Paramethyl Red (p-(p-dimethyl
aminophenylazo)-benzoic acid, sodium salt)

1.0

3.0

red

yellow

ethanol

Metanil Yellow

1.2

2.4

red

yellow

0.01% in water

4-phenylazodiphenylamine

1.2

2.6

red

yellow

0.01% in 0.01 M HCl in 50%ethanol/water

Thymol blue (thymolsulfonephthalein)

1.2

2.8

red

yellow

0.04% in 0.0086 M NaOH

Thymol blue (thymolsulfonephthalein)

8.0

9.6

yellow

blue

0.04% in 0.0086 M NaOH

Metacresol purple
(m-cresolsulfonephthalein)

1.2

2.8

red

yellow

0.04% in 0.01048 M NaOH

Metacresol purple
(m-cresolsulfonephthalein)

7.4

9.0

yellow

purple

0.04% in 0.01048 M NaOH

Orange IV (p-(p-anilinophenylazo)
benzenesulfonic acid, sodium salt)

1.4

2.8

red

yellow

0.01% in water

4-o-tolylazo-o-toluidine

1.4

2.8

orange

yellow

water

Erythrosine, disodium salt

2.2

3.6

orange

red

0.1% in water

Benzopurpurine 48

2.2

4.2

violet

red

0.1% in water

N,N-dimethyl-p-(m-tolylazo)aniline

2.6

4.8

red

yellow

0.1% in water

4,4'-bis(2-amino-1-naphthylazo)2,2'-
stilbenedisulfonic acid

3.0

4.0

purple

red

0.1% in 0.00295 M NaOH

Tetrabromophenolphthaleinethyl ester,
potassium salt

3.0

4.2

yellow

blue

0.1% in ethanol

Bromophenol blue
(3',3",5',5"-tetrabromophenolsulfonephthalein)

3.0

4.6

yellow

blue

0.04% in 0.000596 M NaOH

2,4-dinitrophenol

2.8

4.0

colourless

yellow

saturated in water

N,N-dimethyl-p-phenylazoaniline

2.8

4.4

red

yellow

0.1% in 90% ethanol/water

Congo red

3.0

5.0

blue

red

0.1% in water

Methyl orange-xylene cyanole solution

3.2

4.2

purple

green

ready solution

Methyl orange

3.2

4.4

red

yellow

0.01% in water

Ethyl orange

3.4

4.8

red

yellow

0.05-0.2% in water

4-(4-dimethylamino-1-naphthylazo)-3-
methoxybenzenesulfonic acid

3.5

4.8

violet

yellow

0.1% in 60% ethanol

Bromocresol green (3',3",5',5"-tetrabromo-m-
cresolsulfonephthalein)

3.8

5.4

yellow

blue

0.04% in 0.00572 M NaOH

Resazurin

3.8

6.4

orange

violet

water

4-phenylazo-1-naphthylamine

4.0

5.6

red

yellow

0.1% in ethanol

2-(p-dimethylaminophenylazo)-pyridine

0.2

1.8

yellow

red

0.1% in ethanol

2-(p-dimethylaminophenylazo)-pyridine

4.4

5.6

red

yellow

0.1% in ethanol

4-(p-ethoxyphenylazo)-m-phenylenediamine
monohydrochloride

4.4

5.8

orange

yellow

0.1% in water

Lacmoid

4.4

6.2

red

blue

0.2% in ethanol

Alizarin red S

4.6

6.0

yellow

red

dilute in water

Methyl red

4.8

6.0

red

yellow

0.02% in 60% ethanol/water

Propyl red

4.8

6.6

red

yellow

ethanol

Bromocresol purple
(5',5"-dibromo-o-cresolsulfone-phthalein)

5.2

6.8

yellow

purple

0.04% in 0.0074 M NaOH

Chlorophenol red
(3',3"-dichlorophenolsulfonephthalein)

5.2

6.8

yellow

red

0.04% in 0.00944 M NaOH

p-nitrophenol

5.4

6.6

colourless

yellow

0.1% in water

Alizarin

5.6

7.2

yellow

red

0.1% in methanol

Alizarin

11.0

12.4

red

purple

0.1% in methanol

2-(2,4-dinitrophenylazo)-1-naphthol-3,6-
disulfonic acid, disodium salt

6.0

7.0

yellow

blue

0.1% in water

Bromothymol blue
(3',3"-dibromothymolsulfonephthalein)

6.0

7.6

yellow

blue

0.04% in 0.0064 M NaOH

m-dinitrobenzoylene urea

6.4

8.0

colourless

yellow
Brilliant yellow

6.6

7.8

yellow

orange

1% in water

Phenol red (phenolsulfonephthalein)

6.6

8.0

yellow

red

0.04% in 0.01128 M NaOH

Neutral red

6.8

8.0

red

amb

0.01% in 50% ethanol/water

m-nitrophenol

6.8

8.6

colourless

yellow

0.3% in water

Cresol red (o-cresolsulfonephthalein)

0.0

1.0

red

yellow

0.04% in 0.01048 M NaOH

Cresol red (o-cresolsulfonephthalein)

7.0

8.8

yellow

red

0.04% in 0.01048 M NaOH

Curcumin

7.4

8.6

yellow

red

ethanol

Curcumin

10.2

11.8

 

 

ethanol

Metacresol purple
(m-cresolsulfonephthalein)

1.2

2.8

red

yellow

0.04% in 0.01048 M NaOH

Metacresol purple
(m-cresolsulfonephthalein)

7.4

9.0

yellow

purple

0.04% in 0.01048 M NaOH

4,4'-bis(4-amino-1-naphthylazo)-2,2'-
stilbene disulfonic acid

8.0

9.0

blue

red

0.1% in 0.00295 M NaOH

Thymol blue
(thymolsulfonephthalein)
1.2
2.8
red
yellow
0.04% in 0.0086 M NaOH
Thymol blue
(thymolsulfonephthalein)
8.0
9.6
0.04% in 0.0086 M NaOH
o-cresolphthalein

8.2

9.8

colourless

red

0.04% in ethanol

p-naphtholbenzene

8.2

10.0

orange

blue

1% in dilute alkali

Phenolphthalein

8.2

10.0

colourless

pink

0.05% in 50% ethanol/water

Ethyl-bis(2,4-dimethylphenyl)acetate

8.4

9.6

colourless

blue

saturated solution in 50% acetone/ethanol

Thymolphthalein

9.4

10.6

colourless

blue

0.04% in 50% ethanol/water

Alizarin yellow R (5-(p-
nitrophenylazo)salicylic acid, sodium salt)

10.1

12.0

yellow

red

0.01% in water

p-(2,4-dihydroxyphenylazo)benzene
sulfonic acid, sodium salt)

11.4

12.6

yellow

orange

0.1% in water

5,5'-indigosulfonic acid, disodium salt

11.4

13.0

blue

yellow

water

2,4,6-trinitrotoluene

11.5

13.0

colourless

orange

0.1-0.5% in ethanol

1,3,5-trinitrobenzene

12.0

14.0

colourless

orange

0.1-0.5% in ethanol

Clayton yellow

12.2

13.2

yellow

amb

0.1% in water

 

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Page created by Judy Edwards, Institute of Fundamental Sciences, Massey University

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